Quantum Superposition

Quantum superposition is a fundamental principle of quantum mechanics that states that linear combinations of solutions to the Schrödinger equation are also solutions of the Schrödinger equation.

This follows from the fact that the Schrödinger equation is a linear differential equation in time and position. More precisely, the state of a system is given by a linear combination of all the eigenfunctions of the Schrödinger equation governing that system.

Quantum superposition of states and decoherence

An example is a qubit used in quantum information processing. A qubit state is most generally a superposition of the basis states and :

Where is the quantum state of the qubit and , denote particular solutions to the Schrödinger equation in Dirac notation weighted by the complex numbers and . Here corresponds to the classical 0 bit and to the classical 1 bit. The probabilities of measuring the system in the or state are given by and respectively (see the Born's rule).

The interference fringes in the double-slit experiment provide another example of the superposition principle.

Background

Paul Dirac described the superposition principle as follows:

The general principle of superposition of quantum mechanics applies to the states [that are theoretically possible without mutual interference or contradiction] ... of any one dynamical system. It requires us to assume that between these states there exist peculiar relationships such that whenever the system is definitely in one state we can consider it as being partly in each of two or more other states. The original state must be regarded as the result of a kind of superposition of the two or more new states, in a way that cannot be conceived on classical ideas. Any state may be considered as the result of a superposition of two or more other states, and indeed in an infinite number of ways. Conversely, any two or more states may be superposed to give a new state...

The non-classical nature of the superposition process is brought out clearly if we consider the superposition of two states, A and B, such that there exists an observation which, when made on the system in state A, is certain to lead to one particular result, a say, and when made on the system in state B is certain to lead to some different result, b say. What will be the result of the observation when made on the system in the superposed state? The answer is that the result will be sometimes a and sometimes b, according to a probability law depending on the relative weights of A and B in the superposition process. It will never be different from both a and b [i.e., either a or b]. The intermediate character of the state formed by superposition thus expresses itself through the probability of a particular result for an observation being intermediate between the corresponding probabilities for the original states, not through the result itself being intermediate between the corresponding results for the original states.

Anton Zeilinger, referring to the prototypical example of the double-slit experiment, has elaborated regarding the creation and destruction of quantum superposition:

"[T]he superposition of amplitudes ... is only valid if there is no way to know, even in principle, which path the particle took. It is important to realize that this does not imply that an observer actually takes note of what happens. It is sufficient to destroy the interference pattern, if the path information is accessible in principle from the experiment or even if it is dispersed in the environment and beyond any technical possibility to be recovered, but in principle still ‘‘out there.’’ The absence of any such information is the essential criterion for quantum interference to appear.

Theory

General Formalism

Any state can be expanded as a sum of the eigenstates of an Hermitian operator, like the Hamiltonian, because the eigenstates form a complete basis:

    Quantum Superposition 

where Quantum Superposition  are the energy eigenstates of the Hamiltonian. For continuous variables like position eigenstates, Quantum Superposition :

Quantum Superposition 

where:

Quantum Superposition 

is the projection of the state into the Quantum Superposition  basis and is called the wave function of the particle. In both instances we notice that Quantum Superposition  can be expanded as a superposition of an infinite number of basis states.

Example

Given the Schrödinger equation:

Quantum Superposition 

where Quantum Superposition  indexes the set of eigenstates of the Hamiltonian with energy eigenvalues Quantum Superposition  we see immediately that:

Quantum Superposition 

where:

Quantum Superposition 

is a solution of the Schrödinger equation but is not generally an eigenstate because Quantum Superposition  and Quantum Superposition  are not generally equal. We say that Quantum Superposition  is made up of a superposition of energy eigenstates. Now consider the more concrete case of an electron that is either spin up or down. We now index the eigenstates with the spinors in the Quantum Superposition  basis:

    Quantum Superposition 

where Quantum Superposition  and Quantum Superposition  denote spin up and spin down respectively. As previously discussed the magnitudes of the complex coefficients give the probability of finding the electron in either definite spin state:

    Quantum Superposition 
    Quantum Superposition 
    Quantum Superposition 

Where the probability of finding the particle in either spin up or down is normalized to 1. Notice that Quantum Superposition  and Quantum Superposition  are complex numbers so that:

    Quantum Superposition 

is an allowed state. We now get:

Quantum Superposition .

Quantum Superposition 

Quantum Superposition .

If we consider a qubit with both position and spin, the state is a superposition of all possibilities for both:

    Quantum Superposition 

where we have a general state Quantum Superposition  is the sum of the tensor products of the position space wave functions and spinors.

Hamiltonian evolution

The numbers that describe the amplitudes for different possibilities define the kinematics, the space of different states. The dynamics describes how these numbers change with time. For a particle that can be in any one of infinitely many discrete positions, a particle on a lattice, the superposition principle tells you how to make a state:

    Quantum Superposition 

So that the infinite list of amplitudes Quantum Superposition  completely describes the quantum state of the particle. This list is called the state vector, and formally it is an element of a Hilbert space, an infinite-dimensional complex vector space. It is usual to represent the state so that the sum of the absolute squares of the amplitudes is one:

    Quantum Superposition 

For a particle described by probability theory random walking on a line, the analogous thing is the list of probabilities Quantum Superposition , which give the probability of any position. The quantities that describe how they change in time are the transition probabilities Quantum Superposition , which gives the probability that, starting at x, the particle ends up at y time t later. The total probability of ending up at y is given by the sum over all the possibilities

    Quantum Superposition 

The condition of conservation of probability states that starting at any x, the total probability to end up somewhere must add up to 1:

    Quantum Superposition 

So that the total probability will be preserved, K is what is called a stochastic matrix.

When no time passes, nothing changes: for 0 elapsed time Quantum Superposition , the K matrix is zero except from a state to itself. So in the case that the time is short, it is better to talk about the rate of change of the probability instead of the absolute change in the probability.

    Quantum Superposition 

where Quantum Superposition  is the time derivative of the K matrix:

    Quantum Superposition 

The equation for the probabilities is a differential equation that is sometimes called the master equation:

    Quantum Superposition 

The R matrix is the probability per unit time for the particle to make a transition from x to y. The condition that the K matrix elements add up to one becomes the condition that the R matrix elements add up to zero:

    Quantum Superposition 

One simple case to study is when the R matrix has an equal probability to go one unit to the left or to the right, describing a particle that has a constant rate of random walking. In this case Quantum Superposition  is zero unless y is either x + 1, x, or x − 1, when y is x + 1 or x − 1, the R matrix has value c, and in order for the sum of the R matrix coefficients to equal zero, the value of Quantum Superposition  must be −2c. So the probabilities obey the discretized diffusion equation:

    Quantum Superposition 

which, when c is scaled appropriately and the P distribution is smooth enough to think of the system in a continuum limit becomes:

    Quantum Superposition 

Which is the diffusion equation.

Quantum amplitudes give the rate at which amplitudes change in time, and they are mathematically exactly the same except that they are complex numbers. The analog of the finite time K matrix is called the U matrix:

    Quantum Superposition 

Since the sum of the absolute squares of the amplitudes must be constant, Quantum Superposition  must be unitary:

    Quantum Superposition 

or, in matrix notation,

    Quantum Superposition 

The rate of change of U is called the Hamiltonian H, up to a traditional factor of i:

    Quantum Superposition 

The Hamiltonian gives the rate at which the particle has an amplitude to go from m to n. The reason it is multiplied by i is that the condition that U is unitary translates to the condition:

    Quantum Superposition 
    Quantum Superposition 

which says that H is Hermitian. The eigenvalues of the Hermitian matrix H are real quantities, which have a physical interpretation as energy levels. If the factor i were absent, the H matrix would be antihermitian and would have purely imaginary eigenvalues, which is not the traditional way quantum mechanics represents observable quantities like the energy.

For a particle that has equal amplitude to move left and right, the Hermitian matrix H is zero except for nearest neighbors, where it has the value c. If the coefficient is everywhere constant, the condition that H is Hermitian demands that the amplitude to move to the left is the complex conjugate of the amplitude to move to the right. The equation of motion for Quantum Superposition  is the time differential equation:

    Quantum Superposition 

In the case in which left and right are symmetric, c is real. By redefining the phase of the wavefunction in time, Quantum Superposition , the amplitudes for being at different locations are only rescaled, so that the physical situation is unchanged. But this phase rotation introduces a linear term.

    Quantum Superposition 

which is the right choice of phase to take the continuum limit. When Quantum Superposition  is very large and Quantum Superposition  is slowly varying so that the lattice can be thought of as a line, this becomes the free Schrödinger equation:

    Quantum Superposition 

If there is an additional term in the H matrix that is an extra phase rotation that varies from point to point, the continuum limit is the Schrödinger equation with a potential energy:

    Quantum Superposition 

These equations describe the motion of a single particle in non-relativistic quantum mechanics.

Quantum mechanics in imaginary time

The wave functions of quantum mechanics are probability amplitudes for particular states, and so quantum mechanics lends itself to a statistical description. In a statistical system in discrete time, t=1,2,3, described by a transition matrix for one time step Quantum Superposition , the probability to go between two points after a finite number of time steps can be represented as a sum over all paths of the probability of taking each path:

    Quantum Superposition 

where the sum extends over all paths Quantum Superposition  with the property that Quantum Superposition  and Quantum Superposition . The analogous expression in quantum mechanics is the path integral.

A generic transition matrix in probability has a stationary distribution, which is the eventual probability to be found at any point no matter what the starting point. If there is a nonzero probability for any two paths to reach the same point at the same time, this stationary distribution does not depend on the initial conditions. In probability theory, the probability m for the stochastic matrix obeys detailed balance when the stationary distribution Quantum Superposition  has the property:

    Quantum Superposition 

Detailed balance says that the total probability of going from m to n in the stationary distribution, which is the probability of starting at m Quantum Superposition  times the probability of hopping from m to n, is equal to the probability of going from n to m, so that the total back-and-forth flow of probability in equilibrium is zero along any hop. The condition is automatically satisfied when n=m, so it has the same form when written as a condition for the transition-probability R matrix.

    Quantum Superposition 

When the R matrix obeys detailed balance, the scale of the probabilities can be redefined using the stationary distribution so that they no longer sum to 1:

    Quantum Superposition 

In the new coordinates, the R matrix is rescaled as follows:

    Quantum Superposition 

and H is symmetric

    Quantum Superposition 

This matrix H defines a quantum mechanical system:

    Quantum Superposition 

whose Hamiltonian has the same eigenvalues as those of the R matrix of the statistical system. The eigenvectors are the same too, except expressed in the rescaled basis. The stationary distribution of the statistical system is the ground state of the Hamiltonian and it has energy exactly zero, while all the other energies are positive. If H is exponentiated to find the U matrix:

    Quantum Superposition 

and t is allowed to take on complex values, the K' matrix is found by taking time imaginary.

    Quantum Superposition 

For quantum systems which are invariant under time reversal the Hamiltonian can be made real and symmetric, so that the action of time-reversal on the wave-function is just complex conjugation. If such a Hamiltonian has a unique lowest energy state with a positive real wave-function, as it often does for physical reasons, it is connected to a stochastic system in imaginary time. This relationship between stochastic systems and quantum systems sheds much light on supersymmetry.

Experiments and applications

Successful experiments involving superpositions of relatively large (by the standards of quantum physics) objects have been performed.

  • A "cat state" has been achieved with photons.
  • A beryllium ion has been trapped in a superposed state.
  • A double slit experiment has been performed with molecules as large as buckyballs and functionalized oligoporphyrins with up to 2000 atoms.
  • A 2013 experiment superposed molecules containing 15,000 each of protons, neutrons and electrons. The molecules were of compounds selected for their good thermal stability, and were evaporated into a beam at a temperature of 600 K. The beam was prepared from highly purified chemical substances, but still contained a mixture of different molecular species. Each species of molecule interfered only with itself, as verified by mass spectrometry.
  • An experiment involving a superconducting quantum interference device ("SQUID") has been linked to the theme of the "cat state" thought experiment.
    By use of very low temperatures, very fine experimental arrangements were made to protect in near isolation and preserve the coherence of intermediate states, for a duration of time, between preparation and detection, of SQUID currents. Such a SQUID current is a coherent physical assembly of perhaps billions of electrons. Because of its coherence, such an assembly may be regarded as exhibiting "collective states" of a macroscopic quantal entity. For the principle of superposition, after it is prepared but before it is detected, it may be regarded as exhibiting an intermediate state. It is not a single-particle state such as is often considered in discussions of interference, for example by Dirac in his famous dictum stated above. Moreover, though the 'intermediate' state may be loosely regarded as such, it has not been produced as an output of a secondary quantum analyser that was fed a pure state from a primary analyser, and so this is not an example of superposition as strictly and narrowly defined.
    Nevertheless, after preparation, but before measurement, such a SQUID state may be regarded in a manner of speaking as a "pure" state that is a superposition of a clockwise and an anti-clockwise current state. In a SQUID, collective electron states can be physically prepared in near isolation, at very low temperatures, so as to result in protected coherent intermediate states. What is remarkable here is that there are two well-separated self-coherent collective states that exhibit such metastability. The crowd of electrons tunnels back and forth between the clockwise and the anti-clockwise states, as opposed to forming a single intermediate state in which there is no definite collective sense of current flow.
  • An experiment involving a flu virus has been proposed.
  • A piezoelectric "tuning fork" has been constructed, which can be placed into a superposition of vibrating and non-vibrating states. The resonator comprises about 10 trillion atoms.
  • Recent research indicates that chlorophyll within plants appears to exploit the feature of quantum superposition to achieve greater efficiency in transporting energy, allowing pigment proteins to be spaced further apart than would otherwise be possible.
  • An experiment has been proposed, with a bacterial cell cooled to 10 mK, using an electromechanical oscillator. At that temperature, all metabolism would be stopped, and the cell might behave virtually as a definite chemical species. For detection of interference, it would be necessary that the cells be supplied in large numbers as pure samples of identical and detectably recognizable virtual chemical species. It is not known whether this requirement can be met by bacterial cells. They would be in a state of suspended animation during the experiment.

In quantum computing the phrase "cat state" often refers to the GHZ state, the special entangled state of qubits wherein the qubits are in an equal superposition of all being 0 and all being 1; i.e.,

    Quantum Superposition 


Quantum Computing: Uniform Quantum Superposition States

Uniform quantum superposition states describe quantum systems that exist in a linear combination of multiple basis states, with each basis state contributing equally to the overall superposition.

Definition

In the context of an Quantum Superposition -qubit system, a uniform quantum superposition state is defined as:

Quantum Superposition 
Here, Quantum Superposition  represents the computational basis states of the Quantum Superposition -qubit system, and Quantum Superposition  is the total number of distinct states in the superposition. The normalization factor Quantum Superposition  ensures that the total probability of finding the system in one of the basis states is equal to 1.

Importance in Quantum Computation

Uniform superposition states play a crucial role in quantum computation algorithms. They are often utilized as initial states or intermediate states during quantum computations. The ability to efficiently prepare uniform superposition states is essential for the implementation of various quantum algorithms (e.g., Grover's algorithm, Quantum Fourier Transform), as it impacts the overall efficiency and success of quantum computations.

Preparation of uniform quantum superposition states when Quantum Superposition 


For an Quantum Superposition -qubit system, Hadamard gates acting on each of the Quantum Superposition  qubits (each initialized to the Quantum Superposition ) can be used to prepare uniform quantum superposition states when Quantum Superposition  is of the form Quantum Superposition . In this case case with Quantum Superposition  qubits, the combined Hadamard gate Quantum Superposition  is expressed as the tensor product of Quantum Superposition  Hadamard gates: Quantum Superposition 

The resulting uniform quantum superposition state is then: Quantum Superposition  This generalizes the preparation of uniform quantum states using Hadamard gates for any Quantum Superposition .

Measurement of this uniform quantum state results in a random random state between Quantum Superposition  and Quantum Superposition .

Examples:

Example 1: Quantum Superposition 

For a system with Quantum Superposition  qubit, the Hadamard gate is applied to the single qubit:

Quantum Superposition 

Applying Quantum Superposition  to Quantum Superposition  yields the uniform quantum superposition state: Quantum Superposition 

Example 2: Quantum Superposition 

For a system with Quantum Superposition  qubits, the combined Hadamard gate Quantum Superposition  is the tensor product of two Hadamard gates:

Quantum Superposition 

Mathematically, this is expressed as:

Quantum Superposition 
Applying Quantum Superposition  to Quantum Superposition , yields the superposition states with equal weights.

Preparation of uniform quantum superposition states in the general case, Quantum Superposition Quantum Superposition 

An efficient and deterministic approach for preparing the superposition state

Quantum Superposition 
with a gate complexity and circuit depth of only Quantum Superposition  for all Quantum Superposition  was recently presented. This approach requires only Quantum Superposition  qubits. Importantly, neither ancilla qubits nor any quantum gates with multiple controls are needed in this approach for creating the uniform superposition state Quantum Superposition .


Formal interpretation

Applying the superposition principle to a quantum mechanical particle, the configurations of the particle are all positions, so the superpositions make a complex wave in space. The coefficients of the linear superposition are a wave which describes the particle as best as is possible, and whose amplitude interferes according to the Huygens principle.

For any physical property in quantum mechanics, there is a list of all the states where that property has some value. These states are necessarily perpendicular to each other using the Euclidean notion of perpendicularity which comes from sums-of-squares length, except that they also must not be i multiples of each other. This list of perpendicular states has an associated value which is the value of the physical property. The superposition principle guarantees that any state can be written as a combination of states of this form with complex coefficients.[clarification needed]

Write each state with the value q of the physical quantity as a vector in some basis Quantum Superposition , a list of numbers at each value of n for the vector which has value q for the physical quantity. Now form the outer product of the vectors by multiplying all the vector components and add them with coefficients to make the matrix

    Quantum Superposition 

where the sum extends over all possible values of q. This matrix is necessarily symmetric because it is formed from the orthogonal states, and has eigenvalues q. The matrix A is called the observable associated to the physical quantity. It has the property that the eigenvalues and eigenvectors determine the physical quantity and the states which have definite values for this quantity.

Every physical quantity has a Hermitian linear operator associated to it, and the states where the value of this physical quantity is definite are the eigenstates of this linear operator. The linear combination of two or more eigenstates results in quantum superposition of two or more values of the quantity. If the quantity is measured, the value of the physical quantity will be random, with a probability equal to the square of the coefficient of the superposition in the linear combination. Immediately after the measurement, the state will be given by the eigenvector corresponding to the measured eigenvalue.

Physical interpretation

It is natural to ask why ordinary everyday objects and events do not seem to display quantum mechanical features such as superposition. Indeed, this is sometimes regarded as "mysterious", for instance by Richard Feynman. In 1935, Erwin Schrödinger devised a well-known thought experiment, now known as Schrödinger's cat, which highlighted this dissonance between quantum mechanics and classical physics. One modern view is that this mystery is explained by quantum decoherence.[citation needed] A macroscopic system (such as a cat) may evolve over time into a superposition of classically distinct quantum states (such as "alive" and "dead"). The mechanism that achieves this is a subject of significant research. One mechanism suggests that the state of the cat is entangled with the state of its environment (for instance, the molecules in the atmosphere surrounding it). When averaged over the possible quantum states of the environment (a physically reasonable procedure unless the quantum state of the environment can be controlled or measured precisely), the resulting mixed quantum state for the cat is very close to a classical probabilistic state where the cat has some definite probability to be dead or alive, just as a classical observer would expect in this situation. Another proposed class of theories is that the fundamental time evolution equation is incomplete, and requires the addition of some type of fundamental Lindbladian, the reason for this addition and the form of the additional term varies from theory to theory. A popular theory is continuous spontaneous localization, where the Lindblad term is proportional to the spatial separation of the states. This too results in a quasi-classical probabilistic state.

See also

References

Tags:

Quantum Superposition BackgroundQuantum Superposition TheoryQuantum Superposition Experiments and applicationsQuantum Superposition Quantum Computing: Uniform StatesQuantum Superposition Formal interpretationQuantum Superposition Physical interpretationQuantum Superposition

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