氟化物亚硒酸盐
氟化物亚硒酸盐是一类混合阴离子化合物（英语：Mixed-anion compounds），它同时含有氟离子（F-）和亚硒酸根（SeO32-）离子。
列表
| 名称 | 化学式 | SeO3:F | 分子量 | 晶系 | 空间群 | 晶胞参数（Å） | 晶胞体积 | 密度 | 光学性质 | 参考文献 |
|---|---|---|---|---|---|---|---|---|---|---|
| 氟化亚硒酸钪 | ScSeO3F | 1:1 | triclinic | P1 <13 | −173°C a=6.2769 b=6.5578 c=4.0627 α=95.478 β=95.332 γ=92.363 Z=2 | 3.830 | ||||
| monoclinic | P21/m >13 | a=4.0643 b =6.6109 c=6.32.35 β=93.298° Z=2 | ||||||||
| 氟化四亚硒酸三氧三钛三钠 | Na3Ti3O3(SeO3)4F | 4:1 | hexagonal | P63 | a =12.8439 c =5.2339 | SHG 6 × KDP | ||||
| 二氟化亚硒酸二锰 | Mn2SeO3F2 | 1:2 | 274.83 | orthorhombic | Pnma | a = 7.50848 b = 10.350 and c = 5.47697 Z=4 | pink | |||
| 氟化亚硒酸铁 | FeSeO3F | 1:1 | 201.81 | monoclinic | P21/n | a=4.9559 b=5.2023 c=12.040 β=97.87 Z=4 | 307.50 | 4.359 | yellow | |
| 三氟化二亚硒酸二铁铵 | NH4Fe2F3(SeO3)2 | 2:3 | ||||||||
| 六氟化四亚硒酸四铁哌嗪鎓 | [C4N2H12]Fe4F6(SeO3)4 | 2:3 | 933.40 | monoclinic | C2/c | a=15.168 b=7.3973 c=16.127 β=90.044 Z=5 | 1928.9 | 3.14 | brown | |
| 六氟化四亚硒酸四铁二乙烯三铵 | [C4N3H14]Fe4F6(SeO3)4 | 2:3 | ||||||||
| 二氟化亚硒酸二钴 | Co2SeO3F2 | 1:2 | 282.82 | orthorhombic | Pnma | a = 7.2655 b = 10.001 c = 5.3564 Z=4 | 389.22 | 4.826 | 粉色 | |
| 二氟化亚硒酸二镍 | Ni2(SeO3)F2 | 1:2 | 282.3 | orthorhombic | Pnma | a=7.1727 b=9.9377 c=5.2364 | 373.25 | 黄色 | ||
| 二氟化亚硒酸二铜 | Cu2(SeO3)F2 | 1:2 | 292.05 | orthorhombic | Pnma | a = 7.066 b = 9.590 c = 5.563 Z=4 | 377.0 | 5.146 | 浅绿色 | |
| 二氟化亚硒酸二锌 | Zn2(SeO3)F2 | 1:2 | 295.70 | orthorhombic | Pnma | a=7.276 b=10.042 c=5.256 Z=4 | 384.0 | 5.114 | 无色 | |
| 六氟化亚硒酸二镓三乙烯二铵 | C6H14N2Ga2F6SeO3 | 1:6 | 494.59 | Monoclinic | P21/c | a=12.616 b=7.2700 c=13.605 β=104.746 Z=4 | 1206.8 | 2.722 | colourless | |
| 三氟化亚硒酸镓乙二铵 | C2H10N2GaF3SeO3 | 1:3 | 315.80 | monoclinic | P21/c | a=9.1107 b=8.0382 c=10.8302 β=90.045 Z=4 | 793.1 | 2.2355 | 无色 | |
| 一水合氟化亚硒酸草酸哌嗪鎓 | H2pipGaFSeO3[C2O4]H2O | 1:1 | 409.87 | triclinic | P1 | a=6.377 b=9.2820 c=11.4112 α=66.53 β=77.44 γ=71.89 | 585.47 | 2.325 | colourless | |
| (C4H15N3)2Ga4F2(SeO3)6(C2O4)·4H2O | 6:2 | 1467.11 | triclinic | P1 | a=8.9941 b=9.4963 c=11.2959 α=77.13 β=68.073 γ=83.776 Z=1 | 872.17 | 2.793 | colourless | ||
| 亚硒酸氟化钒酰锶 | Sr(VO2F)(SeO3) | 316.52 | orthorhombic | Pbca | a=9.7816 b=8.0278 c=12.927 Z=8 | 1015.07 | 4.142 | yellow | ||
| 氟化亚硒酸钇 | YSeO3F | 1:1 | monoclinic | P21/c <319 | a=6.5765 b=6.8971 c=7.1728 β=99.036 Z=4 | |||||
| monoclinc | P 21/m >319 | 600° a=6.5840 b=6.9809 c=4.3434 β =95.032 Z=2 | 3.922 | |||||||
| 氟化四亚硒酸三氧三钛三银 | Ag3Ti3O3(SeO3)4F | 1042.15 | hexagonal | P63 | a=12.8975 c=5.2180 Z=2 | 751.70 | 4.604 | colourless SHG 2×KDP | ||
| 二氟化二亚硒酸锆二银 | Ag2ZrF2(SeO3)2 | 598.88 | orthorhombic | Cmca | a=7.3640 b=31.451 c=6.2719 | 1452.6 | 5.477 | colopurless | ||
| 二氟化亚硒酸二镉 | Cd2(SeO3)F2 | 1:2 | 389.76 | orthorhombic | Pnma | a=7.803 b=10.566 c=5.729 Z=4 | 472.4 | 5.480 | 无色 | |
| 三氟化亚硒酸乙二铵 | C2H10N2InF3SeO3 | 360.90 | monoclinic | P21/c | a=9.3066 b=8.3012 c=11.2923 Z=4 | 871.68 | 2.750 | colourless | ||
| 六氟化二亚硒酸三钪铯 | CsSc3F6[SeO3]2 | 2:6 | trigonal | P3m1 | a = 5.6534 c = 10.6987 Z = 1 | |||||
| Cs(TiOF)3(SeO3)2 | 2:3 | 635.53 | hexagonal | P63mc | a=7.2420 c=11.8152 Z=2 | 536.65 | 3.933 | Colourless SHG 5xKDP | ||
| 六氟化二亚硒酸三铁铯 | CsFe3(SeO3)2F6 | 2:6 | trigonal | P3m1 | a=5.459 c=10.537 Z=1 | 271.9 | cyan | |||
| Ba(VO2F)(SeO3) | 366.24 | orthorhombic | Pbca | a=10.0539 b=8.3967 c=13.174 | 1112.18 | 4.375 | yellow | |||
| 氟化亚硒酸镧 | LaSeO3F | 1:1 | monoclinic | P21/c | a = 18.198 b = 7.1575 c = 8.464 β = 96.89 Z = 12 | |||||
| 氟化亚硒酸铈 | CeSeO3F | 1:1 | ||||||||
| 六氟化二亚硒酸硒酸四镨 | Pr4(SeO3)2(SeO4)F6 | 2:6 | monoclinic | C2/c | a = 22.305 b = 7.1054 c = 8.356 β = 98.05° Z = 4 | 浅绿色 | ||||
| 氟化四亚硒酸三镨 | Pr3F[SeO3]4 | 浅绿色 | ||||||||
| Pr5F[SiO4]2[SeO3]3 | 3:1 | triclinic | P1 | a = 7.0114 b = 9.8268 c = 12.8679 α = 70.552 β = 76.904 γ = 69.417° Z = 2 | 5.511 | pale green | ||||
| 氟化四亚硒酸三钕 | Nd3(SeO3)4F | hexagonal | P63mc | a=10.515 c=7.1211 | ||||||
| 氟化四亚硒酸三钐 | Sm3(SeO3)4F | hexagonal | P63mc | a=10.474 c=7.0224 | ||||||
| 氟化四亚硒酸三钆 | Gd3(SeO3)4F | 4:1 | hexagonal | P63mc | a = 10.443 b = 6.9432 Z=2 | |||||
| 氟化四亚硒酸三镝 | Dy3(SeO3)4F | 4:1 | 1014.34 | hexagonal | P63mc | a=10.360 c=6.8647 Z=2 | ||||
| 氟化亚硒酸钬 | HoSeO3F | 1:1 | monoclinic | P21/c | a=6.5784 b=6.8873 c=7.1825 β =99.213 Z=4 | 6.43 | ||||
| Ho3F[SeO3]4 | 4:1 | hexagonal | P63mc | a = 10.3024 c = 6.8037 Z = 2 | ||||||
| 氟化亚硒酸铒 | ErSeO3F | 1:1 | monoclinic | P21/c | a=6.5553 b=6.8741 c=7.1516 β =99.020 Z=4 | 6.54 | ||||
| Er3F[SiO4][SeO3]2 | 2:1 | orthorhombic | Pnna | a = 5.8692 b = 15.2931 c = 10.2967 Z = 4 | pink | |||||
| 氟化亚硒酸铥 | TmSeO3F | 1:1 | monoclinic | P21/c | a=6.5342 b=68607 c=7.1213 β =98,828 Z=4 | 6.63 | ||||
| 氟化亚硒酸镱 | YbSeO3F | 1:1 | monoclinic | P21/c | a=6.5146 b=6.8475 c=7.0924 β =98.637 Z=4 | 6.77 | ||||
| 氟化亚硒酸镥 | LuF[SeO3] | 1:1 | monoclinic | P21/c | −173°C: a=6.4839 b=6.8128 c=7.0581 β=98.657 Z=4 | 308.23 | 6.916 | |||
| triclinic | P1 | a=6.4486 b=6.8441 c=4.2798 α=94.063 β=98.657 γ=91.895 Z=2 | 187.04 | 5.698 | ||||||
| monoclinic | P21/m | 173°C: a=6.4734 b=6.8702 c=4.2843 β=95.602 Z=2 | 189.63 | 5.621 | ||||||
| 氟化四亚硒酸三镥 | Lu3F(SeO3)4 | 4:1 | 1051.75 | trigonal | P63 | a=9.883 c=7.066 Z=2 | 597.7 | 5.844 | 无色，SHG 2.5×KDP | |
| 氟化亚硒酸钒酰铅 | PbVO2(SeO3)F | 1:1 | 436.09 | orthorhombic | Pbca | a=9.812 b=8.147 c=13.026 Z=8 | 1041.3 | 5.563 | 黄色 | |
| 氟化硝酸亚硒酸铅镉 | PbCdF(SeO3)(NO3) | 1:1 | orthorhombic | Pca21 | a=11.121 b=10.366 c=5.3950 Z=4 | 621.9 | 5.634 | SHG 2.6×KDP 带隙 4.42 eV | ||
| 氟化亚硒酸铋 | BiFSeO3 | 1:1 | 354.94 | orthorhombic | Pca21 | a=6.6774 b=6.8872 c=7.4702 Z=4 | 343.54 | 6.862 | 无色， SHG 13.5×KDP | |
| 氟化亚硒酸焦亚硒酸三铋 | Bi3(SeO3)3(Se2O5)F | 3:1 | monoclinic | F21 | SHG 3×KDP | |||||
| 五氟化亚硒酸二铋钾 | KBi2SeO3F5 | 1:5 | 679.02 | orthorhombic | Pbcm | a=4.553 b=17.80 c=8.80 Z=4 | 712.9 | 6.326 | white band gap 4.08 eV | |
| 五氟化亚硒酸二铋铷 | RbBi2SeO3F5 | 1:5 | 725.39 | Triclinic | P1 | a=8.842 b=8.917 c=9.63 α=88.28 β=89.82 γ=89.76 Z=4 | 758.9 | 6.349 | 白色，band gap 4.18 eV | |
| RbBi(SeO3)F2 | 1:2 | 459.41 | orthorhombic | Pnma | a=13.251 b=6.073 c=6.780 Z=4 | 545.6 | ||||
| Bi4TiO2F4(SeO3)4 | 4:4 | 1499.66 | monoclinic | P21/c | a=7.0237 b=6.6824 c=17.3240 β=106.637 Z=2 | 779.07 | 6.393 | 无色 | ||
| Bi4NbO3F3(SeO3)4 | 4:3 | 1541.67 | monoclinic | P21/c | a=7.0448 b=6.6814 c=17.4051 β=106.931 Z=2 | 783.73 | 6.533 | colourless | ||
| Bi4TeO4F2(TeO3)2(SeO3)2 | 2:2 | 1670.64 | monoclinic | P21/c | a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2 | 782.66 | 7.089 | colourless | ||
| Bi2F2(MoO4)(SeO3) | 1:2 | 742.86 | monoclinic | P21/c | a=7.1005 b=9.660 c=12.972 β=12.091 Z=4 | 753.82 | 6.546 | 无色 | ||
| Bi2ZrO2F2(SeO3)2 | 2:2 | 833.10 | triclinic | P1 | a=5.8047 b=6.3469 c=6.7419 α=77.665 β=71.365 γ=72.795 Z=1 | 222.87 | 6.207 | 无色 | ||
| 氟化二亚硒酸铋铅 | PbBi(SeO3)2F | 2:1 | orthorhombic | Pca21 | a=12.9672 b=4.5022 c=11.8221 | SHG 10.5×KDP; band gap 3.75 eV |
参考文献
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