Conservation Of Energy: Law of physics and chemistry

This article refers to the law of conservation of energy in physics. For energy resources sustainably, see: Energy conservation.

Formally, it says that the total amount of energy in an isolated system remains constant, although it may change forms, e.g. friction turns kinetic energy into thermal energy. In thermodynamics, the first law of thermodynamics is a statement of the conservation of energy for thermodynamic systems.

From a mathematical point of view, the energy conservation law is a consequence of the shift symmetry of time; energy conservation is a result of the empirical fact that the laws of physics do not change with time itself. Philosophically, this can be stated as "nothing depends on time per se (time itself)".

Ancient philosophers as far back as Thales of Miletus had the idea that there is some underlying substance of which everything is made. But that is not the same as our concept of "mass-energy" today (for example, Thales thought the underlying substance was water). In 1638, Galileo published his analysis of several situations. This included the famous "interrupted pendulum". This can be described (in modernized language) as conservatively converting potential energy to kinetic energy and back again. However, Galileo did not explain the process in modern terms and had not understood the modern concept either. The German Gottfried Wilhelm Leibniz during 1676-1689 attempted a mathematical formulation of the kind of energy which is connected with motion (kinetic energy). Leibniz noticed that in many mechanical systems (of several masses, m_i each with velocity v_i ),

${\displaystyle \sum _{i}m_{i}v_{i}^{2}}$ 

was conserved so long as the masses did not interact. He called this quantity the vis viva or living force of the system. The principle represents an accurate statement of the approximate conservation of kinetic energy in situations where there is no friction.

 

Meanwhile, in 1843 James Prescott Joule independently discovered the mechanical equivalent in a series of experiments. In the most famous, now called the "Joule apparatus", a descending weight attached to a string caused a paddle immersed in water to rotate. He showed that the gravitational potential energy lost by the weight in descending was approximately equal to the thermal energy (heat) gained by the water by friction with the paddle.

Over the period 1840-1843, similar work was carried out by engineer Ludwig A. Colding though it was little-known outside his native Denmark.

It is easy to see that

${\displaystyle E=KE+PE}$ 

which is also

${\displaystyle E={\frac {1}{2}}mv^{2}+V}$ 

${\displaystyle E={\frac {1}{2}}mx'^{2}+V(x)}$ 

Assuming that ${\displaystyle x'(t)}$  and that ${\displaystyle x(t)}$ , then

${\displaystyle {\frac {dE}{dt}}={\frac {\partial E}{\partial x'}}{\frac {dx'}{dt}}+{\frac {\partial E}{\partial x}}{\frac {dx}{dt}}}$ 

${\displaystyle {\frac {dE}{dt}}=(mx')(x'')-Fx'}$ 

(Since ${\displaystyle V'(x)=-F}$ )

${\displaystyle {\frac {dE}{dt}}=Fx'-Fx'=0}$ 

Therefore, energy does not vary with time.

• Conservation law
• Energy
• Thermodynamics

Modern accounts

• Goldstein, Martin, and Inge F., 1993. The Refrigerator and the Universe. Harvard Univ. Press. A gentle introduction.
• Kroemer, Herbert; Kittel, Charles (1980). Thermal Physics (2nd ed.). W. H. Freeman Company.{{cite book}}: CS1 maint: multiple names: authors list (link) ISBN 0-7167-1088-9
• Nolan, Peter J. (1996). Fundamentals of College Physics, 2nd ed. William C. Brown Publishers.
• Oxtoby & Nachtrieb (1996). Principles of Modern Chemistry, 3rd ed. Saunders College Publishing.
• Papineau, D. (2002). Thinking about Consciousness. Oxford: Oxford University Press.
• Serway, Raymond A.; Jewett, John W. (2004). Physics for Scientists and Engineers (6th ed.). Brooks/Cole.{{cite book}}: CS1 maint: multiple names: authors list (link) ISBN 0-534-40842-7
• Stenger, Victor J. (2000). Timeless Reality. Prometheus Books. Especially chpt. 12. Nontechnical.
• Tipler, Paul (2004). Physics for Scientists and Engineers: Mechanics, Oscillations and Waves, Thermodynamics (5th ed.). W. H. Freeman. ISBN 0-534-40842-7
• Lanczos, Cornelius (1970). The Variational Principles of Mechanics. Toronto: University of Toronto Press. ISBN 0-8020-1743-6

Classic accounts

• Colding, L.A. (1864). "On the history of the principle of the conservation of energy". London, Edinburgh and Dublin Philosophical Magazine and Journal of Science. 27 (179): 56–64. doi:10.1080/14786446408643620.
• Mach, E. (1872). History and Root of the Principles of the Conservation of Energy. Open Court Pub. Co., IL.
• Poincaré, H. (1905). Science and Hypothesis. Walter Scott Publishing Co. Ltd; Dover reprint, 1952., ISBN 0-486-60221-4 Chapter 8, "Energy and Thermo-dynamics"

• MISN-0-158 The First Law of Thermodynamics Archived 2005-10-23 at the Wayback Machine (PDF file) by Jerzy Borysowicz for Project PHYSNET.